Mechanisms of Interfacial Degradation of Epoxy Adhesive/Galvanized Steel Assemblies: Relevance to Durability

• Published in: The Journal of adhesion Vol. 88; no. 2; pp. 145 - 170
• Main Authors: Calvez, P., Bistac, S., Brogly, M., Richard, J., Verchère, D.
• Format: Journal Article
• Language: English
• Published: Taylor & Francis Group 01.02.2012; Taylor & Francis
• Subjects: Chemical Sciences; Corrosion products; Durability; Galvanized steel joint; Interfacial hydrolysis mechanism; Interphase; Material chemistry; Toughened epoxy adhesive; epoxy adhesive; steel; Interfacial degradation
• ISSN: 0021-8464; 1563-518X; 1545-5823
• DOI: 10.1080/00218464.2012.648067

This study reports on the durability of galvanized steel joints bonded with toughened epoxy adhesive formulations under the influence of temperature and moisture aging. The influence of hydrothermal aging on the substrate and adhesive properties was first determined and then correlated to the durability of bonded joints. The mechanical properties of the adhesively bonded joints were assessed by a shear stress-strain analysis on single lap joints. Experimental results have shown a loss of adherence during aging. Scanning electron microscopy, fourier transform infra-red spectroscopy, and differential scanning calorimetry were conducted to analyze precisely the locus of failure and the failure faces after separation of the interface. Consequently, physical and chemical modifications of the adhesive and surface corrosion of the substrate were observed. A three-step mechanism has been proposed to explain the loss of adhesion during aging. The first step was attributed to adhesive and interface hydrolysis of the lap-shear sample's Highly stressed zones, the second step to hydrolysis of the centre of the bonded joint and initiation of corrosion. The last one is due to an important growth of corrosion products which favours rupture in a weak boundary layer at the metal/polymer interphase. The aging model proposed bears out that the higher the corrosion resistance of the metal surface the lower the loss of adhesion under a wet environment.