Rhodium catalyzed C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

The C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by a rhodium complex was studied with a "conjugate addition/β-C cleavage/protonation" strategy. The tandem "conjugate addition/β-C cleavage/protonation" process (CCP) is reported.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 55; no. 84; pp. 1277 - 1271
Main Authors Yang, Xuan, Kong, Wei-Yu, Gao, Jia-Ni, Cheng, Li, Li, Nan-Nan, Li, Meng, Li, Hui-Ting, Fan, Jun, Gao, Jin-Ming, Ouyang, Qin, Xie, Jian-Bo
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 17.10.2019
Royal Society of Chemistry
Subjects
Acetates
Aromatic compounds
Chemistry
Chemistry, Multidisciplinary
Cleavage
Coupling
Physical Sciences
Protonation
Rhodium
Science & Technology
CYCLOADDITION
ACTIVATION
KETONE
METHYL
OLEFINS
CARBON-CARBON BONDS
ARYL
CLEAVAGE
ALKYNES
DERIVATIVES
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Summary:The C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by a rhodium complex was studied with a "conjugate addition/β-C cleavage/protonation" strategy. The tandem "conjugate addition/β-C cleavage/protonation" process (CCP) is reported.
Bibliography:Electronic supplementary information (ESI) available. See DOI
10.1039/c9cc06446j
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc06446j