3D porous and self-supporting Ni foam@graphene@Ni3S2 as a bifunctional electrocatalyst for overall water splitting in alkaline solution

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Vol. 858; p. 113795
• Main Authors: Jin, Chenglong, Zhou, Nan, Wang, Yilong, Li, Xi, Chen, Ming, Dong, Yongzhi, Yu, Zhengsong, Liang, Yani, Qu, Deyu, Dong, Yulin, Xie, Zhizhong, Zhang, Chaocan
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.02.2020; Elsevier Science Ltd
• Subjects: Catalytic activity; Electrocatalysts; Electron conductivity; Graphene; Hydrogen evolution reaction; Hydrogen evolution reactions; Metal foams; Metal sulfides; Nickel foam; Nickel sulfide; Noble metals; Oxygen evolution reaction; Oxygen evolution reactions; Reduced oxide graphene; Tafel slopes; Transition metals; Water splitting; Hydrogen evolution reaction; Water splitting; Reduced oxide graphene; Oxygen evolution reaction; Nickel foam; Nickel sulfide
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2019.113795

Low-cost transition metal sulfides are considered as one kind of the most promising catalysts for the electrochemical water-splitting. In this work, a facile electrochemical method was employed to directly deposit Ni3S2 on Ni foam (NF) decorated with graphene (G) for the construction of a self-supporting electrocatalyst NF@G@Ni3S2 with a 3D porous structure. Due to the intrinsic catalytic activity and continuous NiNi network of Ni3S2, 3D porous structure of NF and the excellent electron conductivity of the graphene as well as their synergistic effects, NF@G-5@Ni3S2 exhibited an excellent electrocatalytic performance. In the alkaline solution, the low overpotentials of 119 and 249 mV were required to reach a current density of 10 mA cm−2 for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), respectively. And the Tafel slopes were only 64.8 and 98.2 mV dec−1 for HER and OER, respectively. Remarkably, by employing NF@G-5@Ni3S2 as both anode and cathode for full water splitting, a very low cell voltage of 1.62 V was needed to reach 10 mA cm−2. Moreover, NF@G-5@Ni3S2 also showed an excellent stability for all HER, OER and overall water-splitting, demonstrating a potential prospect of NF@G-5@Ni3S2 for the practical application. Our work opens up a new direction for the development of non-noble metal electrocatalysts. [Display omitted] •3D porous and self-supporting NF@G@Ni3S2 was constructed by facile electrodeposition.•NF@G-5@Ni3S2 had excellent electrocatalytic performance for HER, OER and water splitting.•NF@G-5@Ni3S2 as anode and cathode for water splitting, only 1.62 V was needed to reach 10 mA cm−2.•NiNi network of Ni3S2, 3D porous structure of NF and excellent electron conductivity of graphene benefits electrocatalysis.