Synthesis of hydrophobic fluorinated polyurethanes and their properties of resistance to cavitation and wear

• Published in: Progress in organic coatings Vol. 104; pp. 11 - 19
• Main Authors: Zhang, Rui-Zhu, Ren, Yang-Yang, Yan, Da-Kao, Guo, Peng-Yan, Li, Lin-Jie
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.03.2017; Elsevier BV
• Subjects: Cavitation erosion; Cavitation resistance; Cohesion; Diphenyl methane diisocyanate; Dosage; Erosion; Ethanol; Flow components; Fluorinated polyurethanes; Fluorination; Fluorine; Hydroelectric power; Hydrophobic; Hydrophobicity; Organic fluorine film; Polyurethane; Polyurethane resins; Pressure; Protective coatings; Resistance to cavitation and wear; Surface energy; Underwater; Water; Water absorption; Water conservation; Water resistance; Resistance to cavitation and wear; Organic fluorine film; Flow components; Fluorinated polyurethanes; Hydrophobic
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2016.12.002

•FPU without hydrophilic CH2OH groups were prepared by introducing fluorine with the method of TEOH-10 for modification of MDI and regulating the dosage and time of the MDI added.•There was organic fluorine membrane which was equivalent to the hydrophobic effect of the lotus leaf on the surface of FPU.•Comprehensive consideration of water conservancy and hydropower engineering application requirements of underwater protective coating, when the molar ratio of TEOH-10 versus MDI was about 0.5, the cavitation erosion amount of FPU reduced from 2.3756×10−3kg to 0.9334×10−3kg, and the cohesive pressure of FPU stayed over 10MPa, which can be used as protective coating of flow components under water. Hydrophobic fluorinated polyurethanes (FPU) without hydrophilic CH2OH groups were prepared by introducing fluorine with the method of perfluoroalkyl ethanols (TEOH-10) for modification of diphenyl-methane-diisocyanates (MDI) and regulating the dosage and time of the MDI added. The experiment of water resistance indicates that the hydrophobicity of the FPU are very strong, owing to the low surface energy of fluorocarbon chains (-CF2CF3) migrating to the surface of material and forming the organic fluorine membrane which was equivalent to the hydrophobic effect of the lotus leaf. Especially when the molar dosage of TEOH-10 was 0.3–0.5 theoretical quantity of MDI, the water absorption of FPU is only between 0.0146% and 0.0182%, and the high cohesive pressure of FPU maintained at 10.31MPa–10.79MPa after 3200h’ water soaking. The erosion wear experiment showes that the anti-erosion performance of FPU continuously improved with the increasing of fluorine content, however, the cohesive pressure of FPU continuously reduced with the increasing of fluorine content. Comprehensive consideration of water conservancy and hydropower engineering application requirements of underwater protective coating, when the molar ratio of TEOH-10 versus MDI was about 0.5, the cavitation erosion amount of FPU reduced from 2.3756×10−3kg to 0.9334×10−3kg, and the cohesive pressure of FPU stayed over 10MPa, which can be used as protective coating of flow components under water.