On the theory of 3D multiple nucleation with kinetic controlled growth

The general theory of the potentiostatic current transients for 3D multiple nucleation with kinetic controlled growth has been analyzed. Analytical expressions for the determination of nucleation/growth parameters have been derived. The cases of instantaneous and progressive nucleation have been con...

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Bibliographic Details
Published inJournal of electroanalytical chemistry (Lausanne, Switzerland) Vol. 818; pp. 265 - 269
Main Authors Isaev, Vladimir A., Grishenkova, Olga V., Zaykov, Yurii P.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.06.2018
Elsevier Science Ltd
Subjects
Crystallization
Current transients
Growth
Growth factors
Kinetics
Mathematical analysis
Nucleation
Overlap
Phase transitions
Current transients
Nucleation
Overlap
Growth
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Summary:The general theory of the potentiostatic current transients for 3D multiple nucleation with kinetic controlled growth has been analyzed. Analytical expressions for the determination of nucleation/growth parameters have been derived. The cases of instantaneous and progressive nucleation have been considered. [Display omitted] •3D multiple nucleation/growth/overlap is discussed.•Equations for potentiostatic current transients are derived.•Formulae for nucleation/growth parameters are proposed.
ISSN:1572-6657
1873-2569
DOI:10.1016/j.jelechem.2018.04.051