The design of TACN-based molecular systems for different supramolecular functions

•Section 1. Recognition and sensing supramolecular functions. Metal complexes of TACN derivatives have been used to develop chemical sensors.•Section 2. Synzymes and nanozymes. The set of 3 donors of TACN reproduces the active site of several metallo-enzymes.•Section 3. Structure and function. TACN...

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Published inCoordination chemistry reviews Vol. 407; p. 213151
Main Authors Macedi, Eleonora, Bencini, Andrea, Caltagirone, Claudia, Lippolis, Vito
Format Journal Article
LanguageEnglish
Published Elsevier B.V 15.03.2020
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Summary:•Section 1. Recognition and sensing supramolecular functions. Metal complexes of TACN derivatives have been used to develop chemical sensors.•Section 2. Synzymes and nanozymes. The set of 3 donors of TACN reproduces the active site of several metallo-enzymes.•Section 3. Structure and function. TACN derivatives in which the structure of ligand/complex is related to function.
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2019.213151