Practical guides for 1H detected solid-state NMR under fast MAS for small molecules

•Practical guide to setup 1H detected solid-state NMR for small molecules under fast MAS is provided.•Basic setup of a fast MAS probe is demonstrated.•Experimental setup together with brief explanation of basic 1D and 2D experiments are demonstrated. This primer article introduces a practical guide...

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Bibliographic Details
Published inJournal of Magnetic Resonance Open Vol. 10-11; p. 100062
Main Authors Nishiyama, Yusuke, Duong, Nghia Tuan
Format Journal Article
LanguageEnglish
Published Elsevier Inc 01.06.2022
Elsevier
Subjects
1H detection
Fast MAS
Heteronuclear correlation
Homonuclear correlation
Solid-state NMR
Solid-state NMR
Homonuclear correlation
1H detection
Fast MAS
Heteronuclear correlation
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Summary:•Practical guide to setup 1H detected solid-state NMR for small molecules under fast MAS is provided.•Basic setup of a fast MAS probe is demonstrated.•Experimental setup together with brief explanation of basic 1D and 2D experiments are demonstrated. This primer article introduces a practical guide for setting up 1H detection solid-state NMR experiments under fast MAS conditions for small molecules. Sample independent adjustment/calibration including magic angle adjustment, shimming, radio-frequency field calibration, Hartmann-Hahn matching adjustments, and 1H heteronuclear decoupling are demonstrated. Experimental setups which depend on samples are also shown for 1H NMR, 1H-1H homonuclear correlation measurements, and 1H-X heteronuclear correlation/distance measurements. Information obtained from each experiment is also highlighted. [Display omitted]
ISSN:2666-4410
2666-4410
DOI:10.1016/j.jmro.2022.100062