An Improved Procedure for Oxidative Cleavage of Oximes to the Corresponding Carbonyl Compounds With Chromic Acid Supported on Kieselguhr Under Viscous Conditions

An improved and efficient oxidative cleavage of oximes to the corresponding carbonyl compounds with chromic acid supported on kieselguhr reagent at room temperature under viscous conditions in the yield between 82% and 96% is described. The present procedure can overcome the problems that existed in...

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Published inSynthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry Vol. 43; no. 10; pp. 1518 - 1520
Main Authors Lin, Fang, Lin, Jianan, Zheng, Wenjin, Lu, Xiu Lian, Lou, Ji-Dong
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 26.11.2013
Subjects
Carbonyl compounds
chromic acid
kieselguhr
oxidative cleavage
oximes
viscous conditions
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Summary:An improved and efficient oxidative cleavage of oximes to the corresponding carbonyl compounds with chromic acid supported on kieselguhr reagent at room temperature under viscous conditions in the yield between 82% and 96% is described. The present procedure can overcome the problems that existed in the common solvent-free reactions as for the difficulty for the solid molecular collision to react.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
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ISSN:1553-3174
1553-3182
DOI:10.1080/15533174.2013.763268