Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers

The paper presents a new polymeric polyoxomolybdate cluster with infinite octamolybdate chains cross-linked by iron (II) centers. The layer-type substance contains sodium cations sandwiched between the [Fe(H2O)4Mo8O27]∞ layers. The structure was determined by single crystal X-ray diffraction analysi...

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Bibliographic Details
Published inOpen Chemistry Vol. 2; no. 2; pp. 323 - 333
Main Authors Patrut, Adrian, Nicoara, Adrian, Margineanu, Dragos, Koop, Michael, Kögerler, Paul, Bögge, Hartmut, Schmidtmann, Marc
Format Journal Article
LanguageEnglish
Published Versita 01.06.2004
De Gruyter
Subjects
layer structure
metal cluster
molybdenum oxide
paramagnetism
polymeric chains
polyoxometalate
X-ray structure
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Summary:The paper presents a new polymeric polyoxomolybdate cluster with infinite octamolybdate chains cross-linked by iron (II) centers. The layer-type substance contains sodium cations sandwiched between the [Fe(H2O)4Mo8O27]∞ layers. The structure was determined by single crystal X-ray diffraction analysis. Magnetic properties, due to the presence of paramagnetic iron (II) centers, are presented and discussed.
ISSN:2391-5420
2391-5420
DOI:10.2478/BF02475576