2-Iodoxybenzoic acid mediated facile conversion of 1,3-diols to 1,2-diketones by oxidative cleavage of the C-C bond

1,3-Diols undergo smooth oxidative cleavage of the C-C bond in the presence of 2-iodoxybenzoic acid (IBX) affording 1,2-diketones in excellent yields under mild conditions.

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Bibliographic Details
Published inSynthesis (Stuttgart) no. 24; pp. 4237 - 4241
Main Authors Yadav, J. S., Biswas, Swapan Kumar, Srinivas, R.
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 18.12.2006
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ORGANIC-SYNTHESIS
REAGENTS
DIELS-ALDER REACTIONS
bond cleavage
COMPLEXES
1,2-diketone
oxidation
1,3-diol
CATALYZED REARRANGEMENT
O-IODOXYBENZOIC ACID
KETONES
2-iodoxybenzoic acid
CHEMISTRY
DERIVATIVES
IBX
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Summary:1,3-Diols undergo smooth oxidative cleavage of the C-C bond in the presence of 2-iodoxybenzoic acid (IBX) affording 1,2-diketones in excellent yields under mild conditions.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2006-950372