Design of TiO2 nanorods and nanotubes doped with lanthanum and comparative kinetic study in the photodegradation of formic acid

Lanthanum doped 1D-TiO2 nanomaterials (nanorods and nanotubes) with tuned structural and textural properties have been evaluated in the photocatalytic degradation of formic acid (FA) under UV conditions. La-doped nanorods and nanotubes calcined at 973K show interesting photocatalytic properties with...

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Bibliographic Details
Published inCatalysis communications Vol. 61; pp. 107 - 111
Main Authors Meksi, M., Berhault, G., Guillard, C., Kochkar, H.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 10.02.2015
Elsevier
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Summary:Lanthanum doped 1D-TiO2 nanomaterials (nanorods and nanotubes) with tuned structural and textural properties have been evaluated in the photocatalytic degradation of formic acid (FA) under UV conditions. La-doped nanorods and nanotubes calcined at 973K show interesting photocatalytic properties with respect to La-free nanomaterials. The presence of La inhibits TiO2 crystallite growth and increases the lifetime of photo-generated electron–hole pairs. [Display omitted] •Evaluation of anisotropic TiO2 materials in the photodegradation of formic acid•Lanthanum slows down the growth of the anatase crystalline domains.•Lanthanum favors the formation of surface oxygen vacancies.•Lanthanum increases the life-time of photo-generated electron–hole pairs.
ISSN:1566-7367
1873-3905
DOI:10.1016/j.catcom.2014.12.020