Enhanced desalination of polyamide thin film nanocomposite incorporated with acid treated multiwalled carbon nanotube-titania nanotube hybrid

• Published in: Desalination Vol. 409; pp. 163 - 170
• Main Authors: Wan Azelee, I., Goh, P.S., Lau, W.J., Ismail, A.F., Rezaei-DashtArzhandi, M., Wong, K.C., Subramaniam, M.N.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.05.2017
• Subjects: Acid treated MWCNT-TNT; Reverse osmosis; Thin film nanocomposite membrane; Water desalination; Reverse osmosis; Water desalination; Thin film nanocomposite membrane; Acid treated MWCNT-TNT
• ISSN: 0011-9164; 1873-4464
• DOI: 10.1016/j.desal.2017.01.029

Polyamide (PA) thin film nanocomposite (TFN) membrane incorporated with multiwalled carbon nanotubes-titania nanotube (MWCNT-TNT) hybrid was successfully fabricated. The hybrid was introduced to the PA selective layer during the interfacial polymerization (IP) of trimesoyl chloride (TMC) and m-phenylenediamine (MPD) monomers over porous commercial polysulfone (PS) ultrafiltration support. The resultant TFN was characterized and applied for desalination. The results revealed that the acid treated MWCNT-TNT, which act as filler in the PA membrane, improved the surface properties of the membrane in term of surface charge, surface roughness and contact angle. Consequently, the water permeability increased significantly without compromising the salt rejection performance. The highest water permeability of 0.74L/m2hbar was achieved for the TFN membrane containing 0.05wt% acid treated MWCNT-TNT, which is approximately 57.45% than that of the neat PA membrane. The NaCl and Na2SO4 rejection of this membrane was 97.97% and 98.07%, respectively that is almost similar to the neat membrane. •Multiwalled carbon nanotubes-titania nanotube hybrid was synthesized by hydrothermal method.•Surface charge of as-synthesized MWCNT-TNT was modified by acid treatment.•TFN was fabricated by incorporating MWCNT-TNT hybrid and applied for RO desalination.•TFN composite membrane exhibited higher flux and salt rejection.