Thermal/Blue Light Induced Cross‐Linking of Acrylic Coatings with Diazo Compounds

• Published in: Macromolecular rapid communications. Vol. 44; no. 21; p. e2300380
• Main Authors: de Zwart, Felix J., Wolzak, Lukas A., Laan, Petrus C. M., Mathew, Simon, Flapper, Jitte, van den Berg, Keimpe J., Reek, Joost N. H., de Bruin, Bas
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.11.2023
• Subjects: Acrylates; Coatings; Crosslinking; Curing; Energy consumption; Heat resistance; High temperature; Material properties; Paints; Photochemicals; Side reactions; Water resistance
• ISSN: 1022-1336; 1521-3927
• DOI: 10.1002/marc.202300380

Abstract The thermal curing of industrial coatings (e.g., car painting and metal coil coatings) is accompanied by a substantial energy consumption due to the intrinsically high temperatures required during the curing process. Therefore, the development of new photochemical curing processes—preferably using visible light—is in high demand. This work describes new diazo‐based cross‐linkers that can be used to photocure acrylic coatings using blue light. This work demonstrates that the structure of the tethered diazo compounds influences the cross‐linking efficiency, finding that side reactions are suppressed upon engineering greater molecular flexibility. Importantly, this work shows that these diazo compounds can be employed as either thermal or photochemical cross‐linkers, exhibiting identical crosslinking performances. The performance of diazo‐cross‐linked coatings is evaluated to reveal excellent water resistance and demonstrably similar material properties to UV‐cured acrylates. These studies pave the way for further usage of diazo‐functionalized cross‐linkers in the curing of paints and coatings.