Fused aromatic networks as a new class of gas hydrate inhibitors

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 433; p. 133691
• Main Authors: Noh, Hyuk-Jun, Lee, Dongyoung, Go, Woojin, Choi, Gyucheol, Im, Yoon-Kwang, Mahmood, Javeed, Seo, Yongwon, Baek, Jong-Beom
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.04.2022
• Subjects: Fused aromatic networks; Gas hydrates; Kinetic hydrate inhibitor; Methane; Porous organic polymers; Fused aromatic networks; Methane; Gas hydrates; Kinetic hydrate inhibitor; Porous organic polymers
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2021.133691

[Display omitted] •Fused aromatic networks are unique subclasses of porous organic polymers.•Fused aromatic networks were examined as kinetic hydrate inhibitors (KHIs).•The V2D-BBL structure showed remarkable performances as a KHI for gas hydrates.•The designed perinone moiety enabled synergistic interactions with host and guest. Fused aromatic networks (FANs) are attracting considerable interest in the scientific community because of their intriguing electronic properties and superior physiochemical stability due to their fully fused aromatic systems. Here, a three-dimensional (3D) cage-like organic network (3D-CON) and a vertical two-dimensional (2D) layered ladder structure (designated as V2D-BBL structure) were studied as materials for gas hydrate inhibitors because of their outstanding stability in high-pressure/low-temperature and periodically incorporated molecular building blocks. The V2D-BBL structure demonstrated remarkable performance, inhibiting the formation of both methane (CH4) and carbon dioxide (CO2) hydrates, comparable to conventional lactam-based polymers. It was determined that the designed perinone moiety in the V2D-BBL structure enables synergistic interactions with the host (water) and guest (CH4) molecules involved in hydrate nucleation. Given their pre-designability and inherent stability, the FANs hold enormous potential as gas hydrate inhibitors for industrial applications.