Co-electrodeposited porous poplar flower-like poly(hydroxymethyl-3,4-ethylenedioxythiophene)/PEG/WS2 hybrid material for high-performance supercapacitor

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Vol. 891; p. 115261
• Main Authors: Liang, Aiqin, Cai, Yue, Wang, Jianxin, Xu, Liming, Zhou, Weiqiang, Xue, Zexu, He, Yao, Xu, Jingkun, Duan, Xuemin
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.06.2021; Elsevier Science Ltd
• Subjects: Capacitance; Electro-polymerization; Electrochemical analysis; Electrode materials; Electron microscopy; Energy storage; Hybrid material; Infrared spectra; Microscopy; Morphology; PEDOT-MeOH; Photoelectrons; Polyethylene glycol; Poplar; Supercapacitor; Supercapacitors; WS2 nanosheet; Supercapacitor; PEDOT-MeOH; Hybrid material; WS2 nanosheet; Electro-polymerization
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2021.115261

[Display omitted] •A porous poplar flower-like PEDOT-MeOH/PEG/WS2 composite was fabricated.•The PEDOT-MeOH/PEG/WS2 showed a high capacitance of 461.5 mF cm−2 at 5 mV s−1.•The device presented a specific energy of 8.72 × 103 μWh cm−2 at 2.62 × 105 μW cm−2.•The capacitive retention was 83.6% after 5000 charge-discharge cycles. The morphology of electrode material is generally critical to affecting their electrochemical performance. Here, a porous poplar flower-like PEDOT-MeOH/PEG/WS2 hybrid material is successfully prepared using a simply co-electrodeposition method. With the assistance of poly(ethylene glycol) (PEG), the chemically exfoliated WS2 nanosheets are doped into poly(hydroxymethyl-3,4-ethylenedioxythiophene) (PEDOT-MeOH) film. The formation of a porous poplar flower-like PEDOT-MeOH/PEG/WS2 composite is proved by scanning electron microscopy, transmission electron microscopy, infrared spectra, energy-dispersive X-ray spectrometry and X-ray photoelectron spectroscopy. The maximum capacitance of the composite reaches 461.5 mF cm−2, which is 1.6 times greater than that of PEDOT-MeOH/PEG film. As-fabricated PEDOT-MeOH/PEG/WS2 composite can keep 85.8% of the initial areal capacitance after 5000 cycles. Additionally, PEDOT-MeOH/PEG/WS2-based symmetrical supercapacitor presents a capacitive capacity of 62.7 mF cm−2 at 0.5 mA cm−2, specific energy of 8.72 × 103 μWh cm−2 at 2.62 × 105 μW cm−2, and capacitive retention of 83.3% after 5000 cycles with a 100% coulombic efficiency. The capacitance improvement of PEDOT-MeOH/PEG/WS2 composite is closely related to porous poplar flower-like structure as well as the cooperation-enhancing effect between PEDOT-MeOH and WS2. These results imply that PEDOT-MeOH/PEG/WS2 composite will have great potential application in the field of the energy storage.