Influence of surface modified ilmenite/melamine formaldehyde composite on the anti-corrosion and mechanical properties of conventional polyamine cured epoxy for internal coating of gas and oil transmission pipelines

• Published in: Progress in organic coatings Vol. 113; pp. 1 - 14
• Main Authors: Abdou, M.I., Ayad, M.I., Diab, A.S.M., Hassan, I.A., Fadl, A.M.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.12.2017; Elsevier BV
• Subjects: Abrasion; Abrasives; Adhesion; Adhesion properties; Adhesion tests; Adhesive strength; Anti-corrosion performance; Bend properties; Blistering; Corrosion; Corrosion prevention; Deformation resistance; Elongation; Epoxy coating; Epoxy coatings; Formulations; Gas pipelines; Ilmenite; Ilmenite/melamine formaldehyde composite; Mechanical properties; Melamine; Melamine formaldehyde resins; Nanocomposites; Natural gas; Particle size distribution; Particulate composites; Petroleum pipelines; Photon correlation spectroscopy; Pipelines; Protective coatings; Quality; SEM; Stiffness; TEM; X-ray diffraction; Adhesion properties; SEM; Epoxy coating; Ilmenite/melamine formaldehyde composite; TEM; Anti-corrosion performance
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2017.08.003

The protection mechanism of IMFC polyamine cured epoxy coating. [Display omitted] •Ilmenite/melamine formaldehyde composite (IMFC) was prepared as modifier for epoxy coating.•XRD pattern confirmed the phase identification of ilmenite particles.•The morphological shape of ilmenite particles was accomplished by SEM and TEM.•The anti-corrosion behavior of IMFC was investigated by salt spray test.•The mechanical properties of IMFC coated films was studied by adhesion, bend, impact and abrasion tests. To support the corrosion protection behavior and mechanical performance properties of conventional epoxy utilized for internal coating of gas and oil transmission pipelines, the present approach was performed to prepare different high build epoxy coating formulations modified using various amounts of processed ilmenite/melamine formaldehyde composite (IMFC) cured by poly amine hardener. X-ray diffraction (XRD) analysis was implemented to assure the phase identification of the crystalline ilmenite particles. Dynamic light scattering measurements were accomplished to measure the particle size distribution of micro-sized ilmenite particles. The lamellar shape of the prepared ilmenite pigment particles (FeTiO3) was illustrated by transmission electron microscope (TEM) investigation. Flaky-like nature and the arrangement in overlapping plates of ilmenite particles were confirmed by scanning electron microscope (SEM) technique. Energy dispersive analysis of X-rays (EDX) was performed to ensure the elemental composition of ilmenite pigment particles. FTIR characteristic spectra for melamine formaldehyde resin, ilmenite/melamine formaldehyde composite (IMFC), conventional polyamine cured epoxy and polyamine cured ilmenite/melamine formaldehyde epoxy composite were done. The anti-corrosion performance properties of the considered IMFC epoxy coating formulations against unmodified blank conventional epoxy were studied by accelerated corrosion experiment (salt spray chamber) after 500h exposure in 5% NaCl solution. The obtained results revealed a significant improvement in the rust grade, blistering size, color tolerance and adhesion strength of IMFC modified epoxy coated steel films with increasing the loading level (%) by weight of the nanocomposite modifier in the coating film. To confirm the previous concept, mass loss method was performed. The mechanical performance properties of these films were investigated by adhesion pull-off, bend, impact and abrasion coating tests to confirm their application efficiency. From the recorded results, the adhesion properties, elongation character, resistance to rapid deformation and film stiffness of these coatings increased significantly with increasing the amount of IMFC modifier.