Core-shell structured Co3O4@NiCo2O4 nanowires on nickel foam for supercapacitors

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Vol. 907; p. 116061
• Main Authors: Yan, A.L., Wang, W.D., Wang, B.Q., Wang, X.C., Cheng, J.P.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.02.2022; Elsevier Science Ltd
• Subjects: Activated carbon; Cobalt oxide; Cobalt oxides; Core-shell structure; Core−shell structures; Electrochemical capacitors; Electrode materials; Electrodes; Energy storage; Flux density; Hydroxides; Lithium; Metal foams; Metal oxides; Nanowires; Nickel; Nickel cobaltite; Nickel compounds; Shell stability; Structural stability; Supercapacitors; Synergistic effect; Cobalt oxide; Core−shell structures; Nickel cobaltite; Electrochemical capacitors
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2022.116061

•A composite film of Co3O4@NiCo2O4 is designed and prepared on Ni foam.•Both components in the 1D core–shell structure are porous.•Impressively comprehensive properties are achieved for the Co3O4@NiCo2O4 electrode.•The hybrid cell exhibits a high energy density and a good stability. As newly developed energy storage devices, high-performance supercapacitors are expected to have large energy densities and it is urgent to design and fabricate novel electrode materials with high capacity and good stability. Core-shell structured hybrid films of Co3O4@NiCo2O4 nanowires were deposited on nickel foam as current collector in this work, different from previously reported assembly manner. The pre-formed NiCo2O4 nanowires on nickel foam as core can serves as conductive paths for the shell material of Co3O4 nanosheets. Since two metal oxides are derived from metal hydroxides by annealing, both components show porous characteristics, benefiting for the diffusion and transportation of electrolyte. Electrochemical measurements demonstrate that the hybrid film has a higher specific capacitance about 995F g−1 at 1 A g−1 than both Co3O4 and NiCo2O4 due to the synergistic effect between two materials, leading to a smaller resistance. An asymmetric cell using activated carbon as negative electrode and the hybrid film as positive electrode delivers an energy density of 36.8 Wh kg−1 at 425 W kg−1 in 1.65 V, showing large potential for energy storage.