A comment on the gurjar mechanism for alkene isomerization using the grubbs olefin metathesis catalysts

The mechanism of allylic alcohol isomerization in the presence of the Grubbs metathesis catalysts is discussed.

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Bibliographic Details
Published inSynlett no. 4; pp. 572 - 576
Main Authors Edlin, CD, Faulkner, J, Fengas, D, Knight, CK, Parker, J, Preece, Quayle, P, Richards, SN
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 04.03.2005
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
RUTHENIUM CARBENE COMPLEXES
TANDEM CATALYSIS
atom transfer
allylic alcohol
isomerization
CARBONYL-COMPOUNDS
BOND FORMATION
Grubbs
metathesis
ALLYLIC ALCOHOLS
HYDROGEN-TRANSFER
C-C
HOMOGENEOUS CATALYSIS
RADICAL POLYMERIZATION
mechanism
REDOX ISOMERIZATION
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Summary:The mechanism of allylic alcohol isomerization in the presence of the Grubbs metathesis catalysts is discussed.
ISSN:0936-5214
1437-2096
DOI:10.1055/s-2005-862384