Synthesis and Crystal Structure of an Iron(II) Complex With Nitronyl Nitroxides

An iron(II) complex with nitronyl nitroxides, [Fe II (NIT4Py) 2 (N(CN) 2 ) 2 (H 2 O) 2 ] (NIT4Py = 2-(4′-pyridyl)- 4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide), was synthesized and characterized by X-ray diffraction analysis, elemental analyses, and IR spectrum. X-ray analysis reveals that the cen...

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Published inSynthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry Vol. 46; no. 2; pp. 206 - 209
Main Authors Wang, Xiaoling, Wen, Guilin, Wang, Fengwu, Chen, Yonghong, Zhao, Xing, Bao, Xia
Format Journal Article
LanguageEnglish
Published Taylor & Francis 01.02.2016
Subjects
crystal structure
Diffraction
Distortion
Fe(II) complex
Hydrogen bonds
Infrared spectroscopy
Nanostructure
nitronyl nitroxide radical
Three dimensional
X-ray spectroscopy
X-rays
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Summary:An iron(II) complex with nitronyl nitroxides, [Fe II (NIT4Py) 2 (N(CN) 2 ) 2 (H 2 O) 2 ] (NIT4Py = 2-(4′-pyridyl)- 4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide), was synthesized and characterized by X-ray diffraction analysis, elemental analyses, and IR spectrum. X-ray analysis reveals that the center Fe(II) ion is six-coordinated with a slightly distorted octahedral geometry. The adjacent monomeric entities are linked by hydrogen bonds to generate a 3D structure.
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ISSN:1553-3174
1553-3182
DOI:10.1080/15533174.2014.963242