Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4

The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh( i ) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) is less than predicted by a series of theoretical calculations, a difference...

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Published inChemical communications (Cambridge, England) Vol. 47; no. 6; pp. 174 - 176
Main Authors Benedict, Jason B, Makal, Anna, Sokolow, Jesse D, Trzop, Elzbieta, Scheins, Stephan, Henning, Robert, Graber, Timothy, Coppens, Philip
Format Journal Article
LanguageEnglish
Published England 14.02.2011
Subjects
Algorithms
Molecular Structure
Organometallic Compounds - chemistry
Photochemistry
Rhodium - chemistry
Synchrotrons
Temperature
Time Factors
X-Ray Diffraction - methods
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Abstract The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh( i ) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice. Structural changes on excitation of a Rh( i ) complex determined by Laue synchrotron pump-probe experiments: blue: ground state; green: excited state.
AbstractList The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) Å is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.
The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh( i ) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice. Structural changes on excitation of a Rh( i ) complex determined by Laue synchrotron pump-probe experiments: blue: ground state; green: excited state.
Author Benedict, Jason B
Henning, Robert
Makal, Anna
Trzop, Elzbieta
Coppens, Philip
Scheins, Stephan
Graber, Timothy
Sokolow, Jesse D
AuthorAffiliation University of Chicago
Chemistry Department
University at Buffalo
The Consortium for Advanced Radiation Sources
State University of New York
University of Aarhus
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– name: a Chemistry Department, University at Buffalo, State University of New York, Buffalo, NY 14260-3000, USA
– name: b Chemistry Department, University of Aarhus, Denmark
– name: c The Consortium for Advanced Radiation Sources, University of Chicago, Chicago, IL 60637, USA
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Snippet The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh( i ) dinuclear...
The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(I) dinuclear complex....
The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump–probe experiments of the triplet excited state of a Rh(I) dinuclear complex....
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SubjectTerms Algorithms
Molecular Structure
Organometallic Compounds - chemistry
Photochemistry
Rhodium - chemistry
Synchrotrons
Temperature
Time Factors
X-Ray Diffraction - methods
Title Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4
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