Time-resolved Laue diffraction of excited species at atomic resolution: 100 ps single-pulse diffraction of the excited state of the organometallic complex Rh2(μ-PNP)2(PNP)2·BPh4
The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh( i ) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) is less than predicted by a series of theoretical calculations, a difference...
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Published in | Chemical communications (Cambridge, England) Vol. 47; no. 6; pp. 174 - 176 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
England
14.02.2011
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Subjects | |
Online Access | Get full text |
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Summary: | The polychromatic Laue technique has been applied in 100 ps delay synchrotron pump-probe experiments of the triplet excited state of a Rh(
i
) dinuclear complex. The observed contraction of the Rh-Rh distance of 0.154 (13) is less than predicted by a series of theoretical calculations, a difference attributed to the constraining effect of the crystal lattice.
Structural changes on excitation of a Rh(
i
) complex determined by Laue synchrotron pump-probe experiments: blue: ground state; green: excited state. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c0cc04997b |