Reversible photoluminescence in spiropyran-modified porous silicon

• Published in: Journal of luminescence Vol. 159; pp. 246 - 250
• Main Authors: Lee, Chen-Yu, Hu, Chih-Hsuan, Cheng, Sheng-Lin, Chu, Chih-Chien, Hsiao, Vincent K.S.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.03.2015
• Subjects: Counting; Data storage; Illumination; Luminescence; Photoluminescence; Porous silicon; Reversible photoluminescence; Ring opening; Spiropyran; Spiropyrans; Wavelengths; Porous silicon; Spiropyran; Reversible photoluminescence
• ISSN: 0022-2313; 1872-7883
• DOI: 10.1016/j.jlumin.2014.11.021

Spiropyran-modified porous silicon (spiro-PS) was used for the first time as an organic–inorganic hybrid material by using reversible photoluminescence (PL). Before spiropyran modification, the peak wavelength from PS was approximately 600nm. Subsequent spiropyran modification strongly quenched the PL intensity, from 15,000 to 2000 counts. However, under UV light irradiation, the PL intensity from spiro-PS was increased gradually to 20,000 counts because of the photoinduced ring opening from a colorless spiropyran (SP-form) to a colored merocyanine (MC-form). Furthermore, the resulting peak wavelength of the PL of an MC–PS sample red-shifted from 600 to 650nm, and the PL intensity was higher than that of unmodified PS. Because the fluorescence emission band (500–700nm) of PS substantially overlapped the absorption band (500–700nm) of the MC-form of spiropyran, the energy transfer from the PS (donor) to the open-ring-state MC-form (acceptor) occurs efficiently. The intensity of the PL from spiro-PS can be reversibly modulated using a heat stimulus. The current demonstrations have potential in reversible solid-state lighting or data storage applications. •Spiropyran-modified porous silicon (spiro-PS) was used for the first time as an organic–inorganic hybrid material with reversible photoluminescence (PL).•UV light irradiation make PL intensity from spiro-PS increased due to the photo-induced ring opening process.•The energy transfer from the PS (donor) to the open-ring state of spiropyran (acceptor) was to be efficient due to the fluorescence emission band of PS substantially overlapped with the absorption band of the ring-opened spiro.•The intensity of the PL from spiro-PS can be reversibly modulated using a heat stimulus.