Transesterification of α-haloesters and β-ketoesters over Mg–Al-hydrotalcites (HT)-like anionic clays

• Published in: Journal of molecular catalysis. A, Chemical Vol. 276; no. 1; pp. 158 - 161
• Main Authors: Bulbule, Vivek J., Borate, Hanumant B., Munot, Yogesh S., Deshpande, Vishnu H., Sawargave, Sangmeshwer P., Gaikwad, Abaji G.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 17.10.2007; Elsevier
• Subjects: Catalysis; Chemistry; Exact sciences and technology; General and physical chemistry; Heterogeneous catalyst; Hydrotalcites; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Transesterification; α-Haloesters; β-Ketoesters; Hydrotalcites; Heterogeneous catalyst; Transesterification; α-Haloesters; β-Ketoesters; Clay; Heterogeneous catalysis; Hydrotalcite; Haloester; Alcohol; Ketoester
• ISSN: 1381-1169; 1873-314X
• DOI: 10.1016/j.molcata.2007.07.006

Transesterification of α-haloesters was achieved by reaction of alcohols in the presence of Mg–Al-HT-like anionic clays. β-Ketoesters were also transesterified under similar conditions on reaction with alcohols with a wide variety of functional groups. ▪ Transesterification of α-haloesters was achieved by reaction of alcohols in the presence of Mg–Al-HT-like anionic clays. β-Ketoesters were also transesterified under similar conditions on reaction with alcohols with a wide variety of functional groups.