Synthesis of polymeric fluorinated sol–gel precursor for fabrication of superhydrophobic coating

• Published in: Applied surface science Vol. 367; pp. 101 - 108
• Main Authors: Li, Qianqian, Yan, Yuheng, Yu, Miao, Song, Botao, Shi, Suqing, Gong, Yongkuan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 30.03.2016
• Subjects: Coating; Fluorination; Fourier transforms; Morphology; Polymeric fluorinated precursor; Precursors; Self-cleaning; Silicon dioxide; Sol gel process; Sol–gel; Superhydrophobic coating; X-rays; Polymeric fluorinated precursor; Self-cleaning; Sol–gel; Superhydrophobic coating
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2016.01.155

•A polymeric fluorinated sol–gel precursor PFT is designed to fabricate superhydrophobic coatings.•The superhydrophobicity could be governed by the concentration of PFT.•Bio-mimicking self-cleaning property similar to lotus leaves could also be achieved. A fluorinated polymeric sol–gel precursor (PFT) is synthesized by copolymerization of 2,3,4,5,5,5-hexafluoro-2,4-bis(trifluorinated methyl)pentyl methacrylate (FMA) and 3-methacryloxypropyltrimethoxysilane (TSMA) to replace the expensive long chain fluorinated alkylsilanes. The fluorinated silica sol is prepared by introducing PFT as co-precursor of tetraethyl orthosilicate (TEOS) in the sol–gel process with ammonium hydroxide as catalyst, which is then used to fabricate superhydrophobic coating on glass substrate through a simple dip-coating method. The effects of PFT concentrations on the chemical structure of the formed fluorinated silica, the surface chemical composition, surface morphology, wetting and self-cleaning properties of the resultant fluorinated silica coatings were studied by using X-ray powder diffraction (XRD), Fourier transform infrared spectrometer (FTIR), X-ray photoelectron spectrophotometer (XPS), scanning electron microscopy (SEM) and water contact angle measurements (WCA). The results show that the fluorinated silica sols are successfully obtained. The size and size distribution of the fluorinated silica particles are found greatly dependent on the concentration of PFT, which play a crucial role in the surface morphology of the corresponding fluorinated silica coatings. The suitable PFT concentration added in the sol–gel stage, i.e. for F-sol-1 and F-sol-2, is helpful to achieve both the low surface energy and multi-scaled microstructures, leading to the formation of the superhydrophobic coatings with bio-mimicking self-cleaning property similar to lotus leaves.