Effects of synthetic phenolic antioxidants on physical, structural, mechanical and barrier properties of poly lactic acid film

• Published in: Carbohydrate polymers Vol. 87; no. 2; pp. 1763 - 1773
• Main Authors: Jamshidian, Majid, Arab Tehrany, Elmira, Cleymand, Franck, Leconte, Stéphane, Falher, Thierry, Desobry, Stéphane
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 15.01.2012; Elsevier
• Subjects: Applied sciences; Atomic force microscopy; Exact sciences and technology; Gas barrier properties; Mechanical properties; Miscellaneous; Organic polymers; Physicochemistry of polymers; Poly lactic acid; Properties and characterization; Synthetic phenolic antioxidants; X-ray photoelectron spectroscopy; Poly lactic acid; Gas barrier properties; Mechanical properties; Atomic force microscopy; X-ray photoelectron spectroscopy; Synthetic phenolic antioxidants; Gallates; Transport properties; Crystallinity; Antioxidant; Experimental study; Transformation temperature; Gas permeability; Lactic acid polymer; Wettability; Steam permeability; Butylated hydroxytoluene; Microroughness; Surface properties; Phenols; Butylated hydroxyanisole; Hydroquinone(butyl); Surface energy; Comparative study
• ISSN: 0144-8617; 1879-1344
• DOI: 10.1016/j.carbpol.2011.09.089

► Synthetic phenolic antioxidants (SPAs) including BHA, BHT, PG and TBHQ tested for their modification effect on Poly lactic acid (PLA). ► PLA properties are not negatively affected by 1% addition of SPAs. ► SPAs can be safely used for PLA antioxidant-active packaging. ► 1% addition of SPAs has not a modification effect on PLA properties. Synthetic phenolic antioxidants (SPAs) including BHA, BHT, PG and TBHQ were added (1%, w/w) to a poly (lactic acid) (PLA) film. SPA addition had no significant effect on the glass transition and melting temperatures of the PLA film but reduced the crystallinity about 26% and the crystallization temperature by 6–12°C from the value of 107°C found for pure PLA film. Young's modulus of PLA film was reduced about 12% by BHA and about 17% by PG and TBHQ. The tensile strength of PLA film also was influenced by BHA, PG and TBHQ. Water vapor permeability of PLA film was not changed by addition of SPAs and PLA oxygen permeability only increased by 30% on BHT addition. No significant changes were observed for surface energy and surface hydrophilicity of PLA films. PLA film microstructures investigated by Atomic force microscopy were significantly changed in term of roughness parameters (Ra and Rq). The results showed that the addition of SPAs in PLA for the creation of active packaging had no negative effect on PLA technical properties.