Effect of alumina percentage on size and superparamagnetic properties of Ni-Al2O3 nanocomposite synthesized by solution combustion

• Published in: Materials & design Vol. 109; pp. 476 - 484
• Main Authors: Nasiri, H., Khaki, J. Vahdati, Shahtahmassebi, N.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 05.11.2016
• Subjects: Aluminum oxide; Combustion; Hysteresis loops; Magnetic properties; Magnetic saturation; Nanocomposites; Nickel; Saturation (magnetic); Solution combustion; TEM; Ureas; VSM; VSM; Solution combustion; Nanocomposites; TEM; Magnetic properties
• ISSN: 0264-1275; 1873-4197
• DOI: 10.1016/j.matdes.2016.07.101

This paper investigates a method to achieve a close to superparamagnetic behavior in Ni-Al2O3 nanocomposite synthesized by solution combustion. The starting materials used are nickel and aluminum nitrates, as oxidizers, and urea, as fuel. Samples with 3, 10, 15, 25, 35 and 45wt.% alumina are produced on a hot plate at 330°C in air. The results show that the change in the content of Al2O3 can change the size of nickel crystallites and particles. The nickel particle size decreased by increasing the alumina content (from about 644nm to 38nm) and resulted in linear hysteresis loops and a relatively high magnetic saturation. The smallest mean nickel particle size measured using TEM images was larger than the critical size that indicates a typical superparamagnetic behavior. The observed linear hysteresis loops and the close to superparamagnetic behavior observed in the nanocomposite are mainly attributed to the combination of two different magnetic behaviors of ferromagnetic nickel and diamagnetic alumina. [Display omitted] •Nanocomposite for 45wt.% Al2O3 showed Hc=30.7Oe and MS=22.007emu/g.•Nickel particles decreased from 644 to 38nm by increasing alumina content from 3 to 45wt.%.•Close to superparamagnetic behavior found in large particles size of nickel (38nm)•Surface area decreased from about 35 to 15m2/g by increasing alumina content.