Liquid-gas phase behavior of polydisperse dipolar hard-sphere fluid: Extended thermodynamic perturbation theory for central force associating potential

• Published in: Condensed matter physics Vol. 15; no. 2; p. 23605
• Main Authors: Kalyuzhnyi, Hlushak, Cummings
• Format: Journal Article
• Language: English
• Published: Institute for Condensed Matter Physics 01.06.2012
• Subjects: associating fluid; ferrocolloids; phase diagram; polydispersity; TPT
• ISSN: 1607-324X
• DOI: 10.5488/CMP.15.23605

The liquid-gas phase diagram for polydisperse dipolar hard-sphere fluid with polydispersity in the hard-sphere size and dipolar moment is calculated using extension of the recently proposed thermodynamic perturbation theory for central force (TPT-CF) associating potential. To establish the connection with the phase behavior of ferrocolloidal dispersions it is assumed that the dipole moment is proportional to the cube of the hard-sphere diameter. We present and discuss the full phase diagram, which includes cloud and shadow curves, binodals and distribution functions of the coexisting daughter phases at different degrees of the system polydispersity. In all cases studied polydispersity increases the region of the phase instability and shifts the critical point to the higher values of the temperature and density. The larger size particles always fractionate to the liquid phase and the smaller size particles tend to move to the gas phase. At relatively high values of the system polydispersity three-phase coexistence is observed.