Chelation-assisted pentafluorophenylation of oximes

The pentafluorophenylation of salicylic aldehyde O-R-oximes is accomplished by their preliminary transformation into difluoroboryl chelate complexes, which react with (C 6F 5) 3SiF in the presence of sodium acetate.

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Bibliographic Details
Published inMendeleev communications Vol. 20; no. 4; pp. 220 - 222
Main Authors Levin, Vitalii V., Gritsenko, Roman T., Dilman, Alexander D., Belyakov, Pavel A., Korlyukov, Alexander A., Arkhipov, Dmitry E., Struchkova, Marina I., Tartakovsky, Vladimir A.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.07.2010
Subjects
Aldehydes
Chelating
Oximes
Sodium acetate
Transformations
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Summary:The pentafluorophenylation of salicylic aldehyde O-R-oximes is accomplished by their preliminary transformation into difluoroboryl chelate complexes, which react with (C 6F 5) 3SiF in the presence of sodium acetate.
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ISSN:0959-9436
DOI:10.1016/j.mencom.2010.06.013