Thermal and mechanical properties of polyamide 11 based composites reinforced with surface modified titanate nanotubes

• Published in: Materials & design Vol. 83; pp. 459 - 467
• Main Authors: Mancic, Lidija, Osman, Renata F.M., Costa, Antonio M.L.M., d’Almeida, Jose R.M., Marinkovic, Bojan A., Rizzo, Fernando C.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15.10.2015
• Subjects: Composite; CTAB; Dispersions; Mechanical properties; Nanotubes; Polyamide 11; Polyamide resins; Polymer matrix composites; Scanning electron microscopy; SDS; Sodium dodecyl sulfate; Surface modification; Titanate nanotubes; Titanates; Surface modification; Polyamide 11; SDS; Titanate nanotubes; Composite; CTAB
• ISSN: 0264-1275; 1873-4197
• DOI: 10.1016/j.matdes.2015.06.059

Improved wettability and dispersibility of titanate nanotubes in polyamide matrix after their surface modification. [Display omitted] •Polyamide 11 composites are reinforced with titanate nanotubes by melt compounding.•Surface modification with CTAB and SDS improves nanotubes interaction with polyamide.•SEM and TEM reveal micro and nano sized inclusions of nanotubes in composites.•Nanotubes increase Td, yield strength, storage and Young’s modulus of composites. The preparation of polyamide 11 (PA11) based composites reinforced with pristine and surface-modified titanate nanotubes (TTNT) is reported. Twin-screw melt compounding was used to produce composites with up to 2wt% of TTNT. To enhance dispersion and TTNT compatibility with the thermoplastic, these were modified with cetyltrimethylammonium bromide (CTAB) and sodium dodecyl sulphate (SDS). Fourier transform infrared spectroscopy and thermogravimetry were used to demonstrate that surface modification prior to composite processing was successful, while scanning transmission electron microscopy combined with energy-dispersive X-ray analysis confirmed the retention of surfactants on TTNT in composites. Nevertheless, scanning and transmission electron microscopy revealed incomplete dispersion of TTNT inside polyamide. The improved wettability on the TTNT–PA11 interface was observed for composites comprising surface-modified TTNT. Consequently, these composites exhibited better thermal and mechanical properties than those containing pristine TTNT. A significant rise of the decomposition temperature was detected in composites containing TTNT modified with CTAB, while the uppermost increment of the storage and Young’s modulus (of about 35% and 26%, respectively) was achieved in the composite comprising 0.5wt% of TTNT modified with SDS. The increase of the nanofiller content improved the yield strength and led to the drop in the strain at break.