Residual stress in as-deposited Al–Cu–Fe–B quasicrystalline thin films

• Published in: Journal of materials research Vol. 27; no. 5; pp. 837 - 844
• Main Authors: Polishchuk, Sergey, Boulet, Pascal, Mézin, André, de Weerd, Marie-Cécile, Weber, Sylvain, Ledieu, Julian, Dubois, Jean-Marie, Fournée, Vincent
• Format: Journal Article
• Language: English
• Published: New York, USA Cambridge University Press 14.03.2012; Springer International Publishing; Springer Nature B.V
• Subjects: Applied and Technical Physics; Biomaterials; Hot pressing; Inorganic Chemistry; Materials elasticity; Materials Engineering; Materials Science; Nanotechnology; Residual stress; Scientific imaging; Studies; Thin films; Physical vapor deposition; Quasicrystal; Coating
• ISSN: 0884-2914; 2044-5326
• DOI: 10.1557/jmr.2011.415

The residual stress in Al–Cu–Fe–B quasicrystalline thin films has been characterized by x-ray diffraction and the curvature method. Films with thicknesses in a range from 0.55 to 2.6 μm were deposited using magnetron sputtering on Si(100) substrates maintained at a temperature of 560 °C. It is found that the tensile stress in uncracked films as determined by the curvature method is close to that measured by a modified sin2ψ method using main diffraction peaks of the icosahedral structure and corresponds approximately to 1.1 GPa. This value is close to that of the thermal stress estimated from the mismatch between thermal expansion coefficients of the film and substrate, suggesting that thermal stress is the main source of residual stress. Increasing film thickness results in the development of cracks and partial delamination of the film, accompanied by the sudden decrease of the stress. The fracture toughness of the quasicrystalline films is estimated between 1.5 and 1.9 MPa$\sqrt {\rm{m}}$.