Unsymmetrical monocyclophosphazenic paddlewheel-shaped host species

A two-step cyclocondensation of different polyoxodiamines in sequence with hexachlorocyclotriphosphazene, N 3P 3Cl 6, yields merged paddlewheel-shaped host cyclophosphazenes which are actually unsymmetrical di-SPIRO macrocyclic species.

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Bibliographic Details
Published inInorganica Chimica Acta Vol. 172; no. 2; pp. 147 - 150
Main Authors Zanin, Bruno, Faucher, Jean-Paul, Labarre, Jean-Francois
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 15.06.1990
Elsevier Science
Subjects
Chemistry
Exact sciences and technology
Organic chemistry
Organometalloidal and organometallic compounds
P derivatives
Preparations and properties
Inorganic heterocycle
Condensation reaction
Nitrogen phosphorus heterocycle
Cyclization
Oxygen nitrogen phosphorus heterocycle
Aliphatic compound
Six membered ring
Dispirane
NMR spectrum
Phosphorus Organic compounds
Macrocycle
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Summary:A two-step cyclocondensation of different polyoxodiamines in sequence with hexachlorocyclotriphosphazene, N 3P 3Cl 6, yields merged paddlewheel-shaped host cyclophosphazenes which are actually unsymmetrical di-SPIRO macrocyclic species.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(00)80849-X