Silver iodide catalyzed the three-component reaction between terminal alkynes, carbon disulfide, and aziridines

A novel catalytic reaction involving terminal alkynes, carbon disulfide, and aziridines has been described. In this transformation, silver-acetylides react with carbon disulfide and aziridines to form 1,4-thiomorpholine molecules in good yields. The optimum conditions developed using silver iodide a...

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Bibliographic Details
Published inJournal of sulfur chemistry Vol. 40; no. 5; pp. 554 - 564
Main Author Samzadeh-Kermani, A.
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis 03.09.2019
Taylor & Francis Ltd
Subjects
Alkynes
aziridine
Carbon
Carbon disulfide
Catalysis
multicomponent reaction
silver salt
terminal alkyne
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Summary:A novel catalytic reaction involving terminal alkynes, carbon disulfide, and aziridines has been described. In this transformation, silver-acetylides react with carbon disulfide and aziridines to form 1,4-thiomorpholine molecules in good yields. The optimum conditions developed using silver iodide and (i-Pr) 2 EtN in DMF at 70°C.
ISSN:1741-5993
1741-6000
DOI:10.1080/17415993.2019.1631316