Some substituted thiourea complexes of molybdenum carbonyl

Preparation of monosubstituted thiourea complexes of molybdenum carbonyl [Mo(CO) 5L] both by thermal and UV irradiation methods have been described. The ligands (L) used were N,N′-dimethylthiourea (DMTU), N,N′-diphenylthiourea (DPTU), tetramethylthiourea (TMTU) and tetraethylthiourea (TETU). The com...

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Bibliographic Details
Published inPolyhedron Vol. 3; no. 2; pp. 235 - 238
Main Authors Baghlaf, A.O., Ishaq, M., Daifuliah, A.S.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 1984
New York, NY Elsevier Science
Subjects
Carbonyl and nitrosyl metals
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
Organic ligand
Ultraviolet visible spectrum
Transition metal Carbonyl Complexes
Infrared spectrum
NMR spectrum
Preparation
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Summary:Preparation of monosubstituted thiourea complexes of molybdenum carbonyl [Mo(CO) 5L] both by thermal and UV irradiation methods have been described. The ligands (L) used were N,N′-dimethylthiourea (DMTU), N,N′-diphenylthiourea (DPTU), tetramethylthiourea (TMTU) and tetraethylthiourea (TETU). The complexes [Mo(CO) 5(L)] were characterised by NMR, IR, UV-visible and elemental analyses.
ISSN:0277-5387
DOI:10.1016/S0277-5387(00)88055-9