Optical sensing of organic vapour based on polymer cholesteric liquid crystal film

A simple, low-cost, and quickly reversible sensor based on polymer cholesteric liquid crystal film (PCLCF) for detecting organic vapour is proposed in this work. PCLCF exhibits an obvious red shift of the reflective colour in the early stages of acetone vapour diffusion and has the ability to quickl...

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Bibliographic Details
Published inLiquid crystals Vol. 47; no. 9; pp. 1390 - 1397
Main Authors Wang, Tsun-Han, Liu, Ming-Fu, Hwang, Shug-June
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis 14.07.2020
Taylor & Francis Ltd
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Summary:A simple, low-cost, and quickly reversible sensor based on polymer cholesteric liquid crystal film (PCLCF) for detecting organic vapour is proposed in this work. PCLCF exhibits an obvious red shift of the reflective colour in the early stages of acetone vapour diffusion and has the ability to quickly recover as vapour is released. The red shift in the transmittance spectrum is attributed to pitch swelling of the PCLCs. The acetone-induced pitch change and response time of the PCLCs, which have been quantitatively characterised, increase with the amount of the adsorbed acetone vapour. This work also revealed a strong correlation between the morphology of the PCLCF and the pitch variation of the helical configuration when subjected to organic vapour. Based on the experimental results, the proposed sensor has the potential to be used for portable and real-time monitoring of organic vapour.
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ISSN:0267-8292
1366-5855
DOI:10.1080/02678292.2020.1720838