Review of the aldol reaction
Aldol condensation is an important synthetic method widely used in organic synthesis. Development of catalytic methods that avoids the production of stoichiometric by-products while maintaining high levels of control available from stoichiometric processes provides an atom-economical alternative for...
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| Published in | Synthetic communications Vol. 46; no. 16; pp. 1327 - 1342 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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Philadelphia
Taylor & Francis
17.08.2016
Taylor & Francis Ltd |
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| Online Access | Get full text |
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| Abstract | Aldol condensation is an important synthetic method widely used in organic synthesis. Development of catalytic methods that avoids the production of stoichiometric by-products while maintaining high levels of control available from stoichiometric processes provides an atom-economical alternative for these important transformations. Indeed, numerous catalysts for the aldol reaction have been reported in recent years, including enzymes, catalytic antibodies, organometals, organocatalysts, and small molecules. The direct aldol reaction is the most important reaction employed by synthetic chemists and is common in nature. Recently, various Lewis acids have been examined as catalysts for aldol reactions, but aldol condensation in a micellar medium has not been studied in detail so far. Because of stronger environmental concerns, organic reactions in green media, especially in water, have attracted more attention. It is believed that micelles act as nano reactors to enhance the reaction rates and give very good to excellent yields of end products. |
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| AbstractList | Aldol condensation is an important synthetic method widely used in organic synthesis. Development of catalytic methods that avoids the production of stoichiometric by-products while maintaining high levels of control available from stoichiometric processes provides an atom-economical alternative for these important transformations. Indeed, numerous catalysts for the aldol reaction have been reported in recent years, including enzymes, catalytic antibodies, organometals, organocatalysts, and small molecules. The direct aldol reaction is the most important reaction employed by synthetic chemists and is common in nature. Recently, various Lewis acids have been examined as catalysts for aldol reactions, but aldol condensation in a micellar medium has not been studied in detail so far. Because of stronger environmental concerns, organic reactions in green media, especially in water, have attracted more attention. It is believed that micelles act as nano reactors to enhance the reaction rates and give very good to excellent yields of end products. |
| Author | Saha, Rumpa Saha, Bidyut Ghosh, Sumanta K. Banerjee, Soujanya Mandal, Swagata Mandal, Sangita Ghosh, Aniruddha |
| Author_xml | – sequence: 1 givenname: Swagata surname: Mandal fullname: Mandal, Swagata organization: Homogeneous Catalysis Laboratory, Department of Chemistry, University of Burdwan – sequence: 2 givenname: Sangita surname: Mandal fullname: Mandal, Sangita organization: Homogeneous Catalysis Laboratory, Department of Chemistry, University of Burdwan – sequence: 3 givenname: Sumanta K. surname: Ghosh fullname: Ghosh, Sumanta K. organization: Homogeneous Catalysis Laboratory, Department of Chemistry, University of Burdwan – sequence: 4 givenname: Aniruddha surname: Ghosh fullname: Ghosh, Aniruddha organization: Homogeneous Catalysis Laboratory, Department of Chemistry, University of Burdwan – sequence: 5 givenname: Rumpa surname: Saha fullname: Saha, Rumpa organization: Department of Chemistry, TDB College Raniganj – sequence: 6 givenname: Soujanya surname: Banerjee fullname: Banerjee, Soujanya organization: Department of Chemistry, St. Xavier's College – sequence: 7 givenname: Bidyut surname: Saha fullname: Saha, Bidyut email: b_saha31@rediffmail.com organization: Homogeneous Catalysis Laboratory, Department of Chemistry, University of Burdwan |
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| Title | Review of the aldol reaction |
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