From isocyanides to trichloropyruvamides: application to a new preparation of oxamide derivatives
[Display omitted] Isocyanides react readily with trichloroacetic acid anhydride forming stable hydrates of trichloropyruvamides. These compounds are valuable intermediates for obtaining oxamides by reaction with TMSCl/NEt 3 followed by addition of an amine.
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Published in | Tetrahedron letters Vol. 45; no. 43; pp. 8047 - 8048 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
OXFORD
Elsevier Ltd
18.10.2004
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | [Display omitted]
Isocyanides react readily with trichloroacetic acid anhydride forming stable hydrates of trichloropyruvamides. These compounds are valuable intermediates for obtaining oxamides by reaction with TMSCl/NEt
3 followed by addition of an amine. |
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ISSN: | 0040-4039 1873-3581 |
DOI: | 10.1016/j.tetlet.2004.08.169 |