Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas

A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N-C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical str...

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Published inMolecules (Basel, Switzerland) Vol. 27; no. 12; p. 3648
Main Authors Pan, Jie, Li, Haocong, Sun, Kai, Tang, Shi, Yu, Bing
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 07.06.2022
MDPI
Subjects
Amides
Catalysts
Decarboxylation
dioxazolones
Experiments
Light
Light effects
Mass spectrometry
phosphinimidic amides
Phosphorylation
Photocatalysis
Scientific imaging
Solvents
Ureas
visible light
dioxazolones
visible light
decarboxylation
ureas
phosphinimidic amides
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Summary:A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N-C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system's ppm Fe.
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ISSN:1420-3049
1420-3049
DOI:10.3390/molecules27123648