An octahedral polyoxomolybdate-organic molecular cage

An unprecedented Mo-organic molecular cage built on interesting {Mo VI 2 O 5 } secondary building blocks and BTC ligands, which has been successfully synthesized and systematically characterized, presents the first example of an isopolyoxomolybdates( vi )-organic molecular cage. An investigation int...

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Published inChemical communications (Cambridge, England) Vol. 57; no. 8; pp. 142 - 145
Main Authors Wang, Xin-Ying, Chen, Wei-Chao, Shao, Kui-Zhan, Wang, Xin-Long, Zhao, Liang, Su, Zhong-Min
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 01.02.2021
Subjects
Cages
Crystallography
Organic chemistry
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Summary:An unprecedented Mo-organic molecular cage built on interesting {Mo VI 2 O 5 } secondary building blocks and BTC ligands, which has been successfully synthesized and systematically characterized, presents the first example of an isopolyoxomolybdates( vi )-organic molecular cage. An investigation into the related Cs + -exchange experiment was performed in detail. An unprecedented Mo-organic molecular cage built from interesting {Mo VI 2 O 5 } SBUs and BTC ligands, which has been successfully synthesized and systematically characterized, presents the first example of an isopolyoxomolybdate-organic molecular cage.
Bibliography:For ESI and crystallographic data in CIF or other electronic format see DOI
Electronic supplementary information (ESI) available: Detailed experimental section and additional figures and characterizations. CCDC
and
2027865
10.1039/d0cc07120j
2027866
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc07120j