Assembly of multifunctional Li4Ti5O12@Co3O4 heterostructures for high-performance Li-ion half/full batteries

• Published in: Journal of alloys and compounds Vol. 856; p. 158110
• Main Authors: Zhang, Jiayu, Wang, Siwei, Xu, Guobao
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 05.03.2021; Elsevier BV
• Subjects: Anodes; Co3O4; Cobalt oxides; Electrochemical analysis; Energy storage; Full battery; Gassing behavior; Heterostructure; Heterostructures; Li4Ti5O12 nanosheets; Lithium; Lithium-ion batteries; Nanocrystals; Reaction kinetics; Rechargeable batteries; Redox reactions; Self-assembly; Tap density; Heterostructure; Li4Ti5O12 nanosheets; Gassing behavior; Full battery; Co3O4
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2020.158110

Spinel Li4Ti5O12 has been attracted extensive attention as an ideal high-rate anode for potential high-power lithium ion batteries. It, however, is still subjects to weaknesses including poor conductivity, sluggish Li+ diffusion and gassing problem, resulting in unsatisfactory electrochemical performance. Now, a 0D/2D heterostructure, cobalt tetraoxide nanocrystals decorated on Li4Ti5O12 nanosheets, was synthesized via a facile self-assembly strategy. Benefiting from hetero-interface effect, suppressed gassing behavior, enhanced tap density and improved redox reaction kinetics, the as-prepared 0D/2D heterostructure shows superior rate capacity of 150 mA h g−1 at 30 C and outstanding cycling stability of retention a capacity of 130 mA h g−1 after 1000 cycles at 20 C when testing as half battery. Furthermore, superior rate properties are also exhibited for the full cell with as-prepared heterostructure anode and commercial LiFePO4 cathode (capacities of 126 and 110 mA h g−1 at 20 C and 30 C, respectively). The noticeable electrochemical performances indicate their promising application as the advanced anode in high-power energy storage fields. In particular, our work develops a cost-effective and scalable synthesis method and will exert significant impact upon constructing other advanced electrodes for high-power LIBs. •A 0D/2D heterostructure, Co3O4 nanocrystals decorated on Li4Ti5O12 nanosheets, was synthesized via a self-assembly strategy.•The improved tap density, suppressed gassing behavior, and enhanced hetero-interface effect are achieved in composite.•The LTO NSs@PCO composite electrode delivers high-rate capacities for Li-ion half/full cells.