Nonaromatic naphthocorroles

New naphthocorrole ligands, display both the cavity size of corroles and the dianionic character of porphyrins. Nonaromatic and yet flaunting deceptively porphyrin-like optical spectra, they are readily accessible via a simple protocol. Previously unknown naphthocorroles possess nonaromatic characte...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 59; no. 36; pp. 5439 - 5442
Main Authors Kielesi ski, ukasz, Summa, Francesco F, Conradie, Jeanet, Honig, Hilah C, Friedman, Ariel, Monaco, Gugliemo, Elbaz, Lior, Ghosh, Abhik, Gryko, Daniel T
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 02.05.2023
Royal Society of Chemistry
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Porphyrins
Science & Technology
ELECTROCHEMISTRY
CORROLE
VALENCE IONIZATION-POTENTIALS
PORPHYRINS
COMPLEXES
METAL
ELECTRONIC-STRUCTURE
GALLIUM
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Summary:New naphthocorrole ligands, display both the cavity size of corroles and the dianionic character of porphyrins. Nonaromatic and yet flaunting deceptively porphyrin-like optical spectra, they are readily accessible via a simple protocol. Previously unknown naphthocorroles possess nonaromatic character, NIR absorption and unusually low-lying LUMO.
Bibliography:1
For ESI and crystallographic data in CIF or other electronic format see DOI
13
2240659
Electronic supplementary information (ESI) available: Synthetic procedures, experimental data, crystallographic data, spectroscopic data, electrochemical data and quantum chemical calculations as well as
F and
https://doi.org/10.1039/d3cc01083j
H
19
C NMR spectra. CCDC
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc01083j