Recent advances of decatungstate photocatalyst in HAT process

The decatungstate anion (W 10 O 32 4− ) appears to exhibit especially interesting properties as a photocatalyst. Because of its unique photocatalytic properties, it is now recognised as a promising tool in organic chemistry. This study examines recent advances in decatungstate chemistry, primarily c...

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Published inOrganic & biomolecular chemistry Vol. 22; no. 13; pp. 2523 - 2538
Main Authors Singh, Praveen P, Sinha, Surabhi, Gahtori, Prashant, Tivari, Shraddha, Srivastava, Vishal
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 27.03.2024
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Summary:The decatungstate anion (W 10 O 32 4− ) appears to exhibit especially interesting properties as a photocatalyst. Because of its unique photocatalytic properties, it is now recognised as a promising tool in organic chemistry. This study examines recent advances in decatungstate chemistry, primarily concerned with synthetic and, to some degree, mechanistic challenges. In this short review we have selected to give a number of illustrative examples that demonstrate the various applications of decatungstate in the hydrogen atom transfer (HAT) process. The decatungstate anion (W 10 O 32 4− ) appears to exhibit especially interesting properties as a photocatalyst.
Bibliography:Praveen P. Singh is working as Assistant Professor in the Department of Chemistry at the United College of Engineering and Research, Prayagraj, India. He obtained his B.Sc. and M.Sc. degrees in organic chemistry from T. D. P. G. College (V. B. S. Purvanchal University) Jaunpur and D.Phil. from the Department of Chemistry, University of Allahabad, India. His current research interests include the development of synthetic receptors for the recognition of biological target structures and the application of visible light chemical photocatalysis towards organic synthesis as well as nanophotocatalysis.
Shraddha Tivari has completed B.Sc. and M.Sc. degrees in organic chemistry from the Department of Chemistry, University of Allahabad. Currently, she is pursuing research work under the supervision of Dr Vishal Srivastava, from the Department of Chemistry, C. M. P. College, University of Allahabad, India. Her research interest is mainly focused on visible light-induced formation of C-C and C-heteroatom bonds.
Vishal Srivastava is working as Assistant Professor, Department of Chemistry, C. M. P. College (Constituent P.G. College of Central University of Allahabad) Prayagraj, India. He has completed graduation (B.Sc.), post-graduation (M.Sc.) in organic chemistry and doctoral degree (D.Phil.) from the Department of Chemistry, University of Allahabad, India. His current research work involves the designing of novel biologically active photoredox-catalyzed synthetic organic compounds.
Surabhi Sinha is presently working as an Assistant Professor in the Department of Chemistry, United College of Engineering & Research, Naini, Prayagraj. She has completed her graduation, post-graduation and D.Phil. from University of Allahabad, Prayagraj. Her area of research interest mainly includes quaternary complexes of biochemical significance and organic synthetic transformations. She is a life member of several professional bodies.
Prashant Gahtori has received higher education and training, postdoc/Ph.D. from the top NIRF-ranked Government Institutions of India. He was also recognized as "Best Researcher" among all international participants, hailing from all over the world at Loughborough University, United Kingdom. He is currently a Professor at Graphic Era Hill University Dehradun. His research interest is in computer medicinal chemistry, synthesis, and biological activity.
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ISSN:1477-0520
1477-0539
DOI:10.1039/d4ob00213j