Gold-based enantioselective bimetallic catalysis
Multimetallic catalysis is a powerful strategy to access complex molecular scaffolds efficiently from easily available starting materials. Numerous reports in the literature have demonstrated the effectiveness of this approach, particularly for capitalizing on enantioselective transformations. Inter...
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| Published in | Chemical communications (Cambridge, England) Vol. 59; no. 52; pp. 87 - 816 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
27.06.2023
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Multimetallic catalysis is a powerful strategy to access complex molecular scaffolds efficiently from easily available starting materials. Numerous reports in the literature have demonstrated the effectiveness of this approach, particularly for capitalizing on enantioselective transformations. Interestingly, gold joined the race of transition metals very late making its use in multimetallic catalysis unthinkable. Recent literature revealed that there is an urgent need to develop gold-based multicatalytic systems based on the combination of gold with other metals for enabling enantioselective transformations that are not possible to capitalize with the use of a single catalyst alone. This review article highlights the progress made in the field of enantioselective gold-based bimetallic catalysis highlighting the power of multicatalysis for accessing new reactivities and selectivities which are beyond the reach of individual catalysts.
Multimetallic catalysis is a powerful strategy to access complex molecular scaffolds efficiently from easily available starting materials. |
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| Bibliography: | Nitin T. Patil was born in Jalgaon (Maharashtra), India, in 1975. He completed his doctoral studies from the University of Pune in 2002 under the supervision of Prof. Dilip D. Dhavale. Subsequently, he joined Prof. Christoph Schneider's group as a postdoctoral fellow at the University of Goettingen, Germany. In November 2002, he moved to Tohoku University, Japan, as a JSPS postdoctoral fellow to work with Prof. Yoshinori Yamamoto, where later on he was appointed as an Assistant Professor. In June 2006, he joined Prof. K. C. Nicolaou's laboratory at ICES, Singapore, and later at The Scripps Research Institute, USA. He began his independent career in September 2008 at CSIR-IICT, Hyderabad, and subsequently moved to CSIR-NCL, Pune, in August 2013. Since July 2017, he has been an Associate Professor at the Department of Chemistry, IISER Bhopal. Shivhar B. Ambegave was born in 1992 in Nanded (Maharashtra), India. In 2016, he completed his MSc (Organic Chemistry) from the Yeshwant Mahavidyalaya, which is affiliated to Swami Ramanand Teerth Marathwada University, Nanded. In 2018, he started his PhD at IISER Bhopal under the supervision of Dr Nitin T. Patil, where he is focusing on the development of new strategies based on enantioselective gold catalysis. Shubham was born in 2002 in Sikanderpur (Haryana), India. He is currently pursuing his BS-MS degree at the Indian Institute of Science Education and Research Bhopal (IISER Bhopal). He is associated with Dr Nitin T. Patil's laboratory since May, 2022. Tushar R. More was born in Dhule (Maharashtra), India, in 1998. He completed his MSc in Chemistry from (NIT) National Institute of Technology Jamshedpur (Jharkhand), India, in 2022. He carried out his Winter Research Internship at Indian Institute of Science Education and Research (IISER) Bhopal under the supervision of Dr Nitin T. Patil in December 2022. ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-3 content type line 23 ObjectType-Review-1 |
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/d3cc01966g |