Simultaneous stirring and microwave assisted synthesis of nanoflakes MnO2/rGO composite electrode material for symmetric supercapacitor with enhanced electrochemical performance

• Published in: Diamond and related materials Vol. 110; p. 108129
• Main Authors: Vimuna, V.M., Athira, A.R., Dinesh Babu, K.V., Xavier, T.S.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.12.2020; Elsevier BV
• Subjects: Capacitance; Composites; Electrochemical analysis; Electrode materials; Electrodes; Energy storage; Flux density; Graphene; Infrared analysis; Manganese dioxide; Porous morphology; Reduced graphene oxide; Spectrum analysis; Stirring; Supercapacitor; Supercapacitors; Synthesis; Transition metal oxides; Porous morphology; Supercapacitor; Transition metal oxides; Composites; Reduced graphene oxide; Energy storage
• ISSN: 0925-9635; 1879-0062
• DOI: 10.1016/j.diamond.2020.108129

Nanoflakes MnO2/reduced graphene oxide (NMG) composite and MnO2 nanoflakes (MN) were successfully synthesized through a modified method in which periodic repetition of stirring and microwave irradiation simultaneously were done for 21 cycles. The as-synthesized samples were characterized using X-ray diffraction, Fourier transformed infrared spectroscopy, Scanning electron microscopy, Energy-dispersive X-ray spectroscopy and Brunauer-Emmett-Teller analysis. Symmetric supercapacitors were fabricated using prepared MN and NMG composite as electrode materials. The NMG symmetric supercapacitor exhibited higher specific capacitance (140.3 Fg−1at 1 mA) and specific capacitance retention (91%) than MN symmetric supercapacitor. At the same time, the NMG symmetric supercapacitor also delivered a maximum energy density of 19.5 Wh kg−1at a power density of 633.7 W kg−1and remained 17 Wh kg−1 at 1864.3 W kg−1. Moreover, the efficiency of this composite symmetric supercapacitor is 99.4% retained even after 5000 charge/discharge cycles at 2 mA current. [Display omitted] •NMG composite was prepared through a periodic repetition of simultaneous stirring and microwave irradiation for 21 cycles.•The NMG composite symmetric supercapacitor achieved a high specific capacitance of 140.3 Fg-1 at 1 mA current.•It also exhibited outstanding cyclic stability of 99.4% efficiency after 5000 charge/discharge cycles at 2 mA current.