Chiroptical induction with prism[5]arene alkoxy-homologs

The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 10 7 M −1 , significant CD with g abs of up to 0.8 × 10 −2 and CPL with g lum of 2 × 10 −3 . The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with...

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Published inChemical communications (Cambridge, England) Vol. 58; no. 98; pp. 13584 - 13587
Main Authors Liang, Xiaotong, Shen, Yanling, Zhou, Dayang, Ji, Jiecheng, Wang, Hongtao, Zhao, Ting, Mori, Tadashi, Wu, Wanhua, Yang, Cheng
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 08.12.2022
Subjects
Amino acids
Aromatic compounds
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Summary:The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 10 7 M −1 , significant CD with g abs of up to 0.8 × 10 −2 and CPL with g lum of 2 × 10 −3 . The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with the substituents on the prism[5]arenes. The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 10 7 M −1 , significant CD with g abs of up to 0.8 × 10 −2 and CPL with g lum of 2 × 10 −3 .
Bibliography:https://doi.org/10.1039/d2cc05690a
Electronic supplementary information (ESI) available. See DOI
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc05690a