Mild Conditions for Oxidation/Epoxidation of Styrene

In this study, in order to obtain novel support materials for immobilization of transition metals, polymeric Schiff bases were synthesized using a poly-condensation reaction between ortho(o-)phthalaldehyde tere(t-)phthalaldehyde, oxaldehyde and diamines like, e.g., ethylene-p-phenylene- and o-phenyl...

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Bibliographic Details
Published inDesigned monomers and polymers Vol. 14; no. 6; pp. 559 - 570
Main Authors Kazanci, A., Saribiyik, O.Y., Serin, S.
Format Journal Article
LanguageEnglish
Published Taylor & Francis Group 01.01.2011
Subjects
CATALYTIC ACTIVITY
OXIDATION
SCHIFF BASE
STYRENE
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Summary:In this study, in order to obtain novel support materials for immobilization of transition metals, polymeric Schiff bases were synthesized using a poly-condensation reaction between ortho(o-)phthalaldehyde tere(t-)phthalaldehyde, oxaldehyde and diamines like, e.g., ethylene-p-phenylene- and o-phenylenediamine. Additionally, catalytic activity of polymeric Schiff base metal on oxidation/epoxidation of styrene complexes were investigated. The products have been characterized on the basis of analytical and spectral method, Fourier transform infrared spectroscopy, 1 H- and 13 C-nuclear magnetic resonance, gel-permeation chromatography, elemental analysis, thermogravimetric analysis, atomic adsorbtion spectrometry, gas chromatography and gas chromatography mass spectrometry.
ISSN:1568-5551
1568-5551
DOI:10.1163/156855511X598641