Crown ether-like octanuclear molybdenum() clusters for cation binding and gas adsorption

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 53; no. 21; pp. 898 - 8987
• Main Authors: Dai, Ru-Dan, Xie, Zhen-Lang, Liu, Cheng, Xin, Dong, Zhou, Zhao-Hui
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 28.05.2024
• Subjects: Adsorption; Bonding strength; Cations; Crown ethers; Hydrogen bonds; Molybdenum; Oxygen atoms; Porous materials; Reducing agents

Octanuclear polyoxomolybdenum-based porous materials, Na 8 [Mo 8 O 8 (μ 2 -O) 8 (μ 2 -OH) 8 (3-apz) 4 ] 2 ·26H 2 O ( 1 , 3-Hapz = 3-aminopyrazole), K 8 [Mo 8 O 8 (μ 2 -O) 8 (μ 2 -OH) 8 (3-apz) 4 ] 2 ·7H 2 O ( 2 ) and (NH 4 ) 4 [Mo 8 O 8 (μ 2 -O) 8 (μ 2 -OH) 4 (3-apz) 8 ]·20.5H 2 O ( 3 ), have been s...