Rhodium metallene-supported platinum nanocrystals for ethylene glycol oxidation reaction

• Published in: Nanoscale Vol. 15; no. 4; pp. 1947 - 1952
• Main Authors: Zhao, Yue, Yuan, Zi-Han, Huang, Jiang-Tao, Wang, Ming-Yao, He, Bin, Ding, Yu, Jin, Pu-Jun, Chen, Yu
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 27.01.2023
• Subjects: Chemical properties; Chemical reduction; Chemical synthesis; Electric vehicles; Electrocatalysts; Electronic devices; Ethylene glycol; Fuel cells; Low temperature; Nanocrystals; Nanoparticles; Noble metals; Oxidation; Platinum; Portable equipment; Rhodium
• ISSN: 2040-3364; 2040-3372; 2040-3372
• DOI: 10.1039/d2nr06138d

Low-temperature fuel cells have great application potential in electric vehicles and portable electronic devices, which need advanced electrocatalysts. Controlling the composition and morphology of electrocatalysts can effectively improve their catalytic performance. In this work, a Rh metallene (Rhlene)-supported Pt nanoparticle (Pt/Rhlene) electrocatalyst is successfully synthesized by a simple chemical reduction method, in which ultra-small Pt nanoparticles are uniformly attached to the Rhlene surface due to the high surface area of Rhlene. Pt/Rhlene reveals a 3.60-fold Pt-mass activity enhancement for the ethylene glycol oxidation reaction in alkaline solution compared with commercial Pt black, and maintains high stability and excellent poisoning-tolerance during electrocatalysis, owing to the specific physical/chemical properties of Rhlene. The superior electrocatalytic performance of Pt/Rhlene may open an avenue to synthesize other metallene-supported noble metal nanoparticle hybrids for various electrocatalytic applications. In this work, Rh metallene (Rhlene) with a high surface area was successfully used to support Pt nanoparticles (Pt/Rhlene). Pt/Rhlene revealed better performance for ethylene glycol oxidation reaction in alkaline solution than Pt black.