Modulating confinement space in metal-organic frameworks enables highly selective indole C3-formylation

Here, Selective C3-formylation of indole was achieved under mild conditions using a metal-organic framework (MOF) catalyst. The confined reaction space within the MOF pores effectively suppressed undesired side reactions and promoted the formation of the targeted product by controlling the reaction...

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Published inChemical communications (Cambridge, England) Vol. 6; no. 44; pp. 5715 - 5718
Main Authors Zheng, Deng-Yue, Zhang, Tianjian, Bai, Rongxian, Li, Minghao, Gu, Yanlong
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 28.05.2024
Subjects
Density functional theory
Metal-organic frameworks
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Abstract Here, Selective C3-formylation of indole was achieved under mild conditions using a metal-organic framework (MOF) catalyst. The confined reaction space within the MOF pores effectively suppressed undesired side reactions and promoted the formation of the targeted product by controlling the reaction pathway. Density functional theory (DFT) calculations corroborated the experimental observations. MOF confinement catalysis can hinder the reaction of orthoformate and indole to form the trimethoxymethane compounds, thereby creating indole C3 formaldehyde compounds.
AbstractList Here, Selective C3-formylation of indole was achieved under mild conditions using a metal–organic framework (MOF) catalyst. The confined reaction space within the MOF pores effectively suppressed undesired side reactions and promoted the formation of the targeted product by controlling the reaction pathway. Density functional theory (DFT) calculations corroborated the experimental observations.
Here, Selective C3-formylation of indole was achieved under mild conditions using a metal-organic framework (MOF) catalyst. The confined reaction space within the MOF pores effectively suppressed undesired side reactions and promoted the formation of the targeted product by controlling the reaction pathway. Density functional theory (DFT) calculations corroborated the experimental observations.Here, Selective C3-formylation of indole was achieved under mild conditions using a metal-organic framework (MOF) catalyst. The confined reaction space within the MOF pores effectively suppressed undesired side reactions and promoted the formation of the targeted product by controlling the reaction pathway. Density functional theory (DFT) calculations corroborated the experimental observations.
Here, Selective C3-formylation of indole was achieved under mild conditions using a metal-organic framework (MOF) catalyst. The confined reaction space within the MOF pores effectively suppressed undesired side reactions and promoted the formation of the targeted product by controlling the reaction pathway. Density functional theory (DFT) calculations corroborated the experimental observations. MOF confinement catalysis can hinder the reaction of orthoformate and indole to form the trimethoxymethane compounds, thereby creating indole C3 formaldehyde compounds.
Author Li, Minghao
Gu, Yanlong
Zheng, Deng-Yue
Bai, Rongxian
Zhang, Tianjian
AuthorAffiliation Ministry of Education
Key Laboratory of Material Chemistry for Energy Conversion and Storage
Shihezi University
Hubei Key Laboratory of Material Chemistry and Service Failure
Huazhong University of Science and Technology
School of Chemistry and Chemical Engineering
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Snippet Here, Selective C3-formylation of indole was achieved under mild conditions using a metal-organic framework (MOF) catalyst. The confined reaction space within...
Here, Selective C3-formylation of indole was achieved under mild conditions using a metal–organic framework (MOF) catalyst. The confined reaction space within...
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SubjectTerms Density functional theory
Metal-organic frameworks
Title Modulating confinement space in metal-organic frameworks enables highly selective indole C3-formylation
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