Two-dimensional titanium carbide (TiCT) MXenes to inhibit the shuttle effect in sodium sulfur batteries
Room-temperature sodium sulfur batteries (RT-NSBs) are among the promising candidates for large-scale energy storage applications because of the natural abundance of the electrode materials and impressive energy density. However, one of the main technical challenges of RT-NSBs is the shuttle effect...
Saved in:
Published in | Physical chemistry chemical physics : PCCP Vol. 24; no. 7; pp. 4187 - 4195 |
---|---|
Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
England
Royal Society of Chemistry
16.02.2022
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | Room-temperature sodium sulfur batteries (RT-NSBs) are among the promising candidates for large-scale energy storage applications because of the natural abundance of the electrode materials and impressive energy density. However, one of the main technical challenges of RT-NSBs is the shuttle effect by which active redox intermediates (
i.e.
, sodium polysulfides Na
2
S
n
,
n
= 1-8) are dissolved in electrolytes, which hamper the battery reversibility. The interfacial interplays between Na
2
S
n
and the electrodes (or electrolytes) at the atomic level thus play an intrinsic role in elucidating the shuttle effect. This work reports the
ab initio
calculations to unravel the suppression of the shuttle effect using titanium carbide MXenes (Ti
3
C
2
T
x
, T
x
= F, O) as the cathode additives. The findings reveal that the shuttle phenomenon is efficiently resolved because the immense chemical bonding of Na
2
S
n
-Ti
3
C
2
T
x
interfaces competitively surpasses the binding magnitudes of Na
2
S
n
-electrolyte interaction. The analysis of the electronic density of states and charge density further manifests that there is charge donation from the Na-3s orbital of Na
2
S
n
to the unfilled F(O)-2p orbitals of metallic Ti
3
C
2
T
x
. The metallicity of the Ti
3
C
2
T
x
remains preserved during the entire course of the redox process, ensuring the rapid electrochemical kinetics. Furthermore, the presence of Ti
3
C
2
T
x
additives drastically reduces the dissociation barrier of the final redox product Na
2
S, yielding the efficient utilization of sulfur during the discharge process. This work has proposed the unexplored functionality of Ti
3
C
2
T
x
as the anchoring materials for RT-NSBs.
Room-temperature sodium sulfur batteries (RT-NSBs) are among the promising candidates for large-scale energy storage applications because of the natural abundance of the electrode materials and impressive energy density. |
---|---|
Bibliography: | 10.1039/d1cp05300k Electronic supplementary information (ESI) available. See DOI ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1463-9076 1463-9084 |
DOI: | 10.1039/d1cp05300k |