Effect of evaporated Sb layer on performance of flexible CZTSSe thin film solar cell

•Evaporated Sb layer was inserted into CZTSSe precursor for the first time.•Hole concentration in CZTSSe was found to increase with Sb layer thickness.•The grain growth of CZTSSe benefited a lot from the introduced Sb layer.•The electrostatic potential fluctuation was reduced after the incorporation...

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Bibliographic Details
Published inSolar energy Vol. 193; pp. 267 - 274
Main Authors Sun, Luanhong, Shen, Honglie, Huang, Hulin, Raza, Adil, Zhao, Qichen
Format Journal Article
LanguageEnglish
Published New York Elsevier Ltd 15.11.2019
Pergamon Press Inc
Subjects
CZTSSe
Electrostatic properties
Evaporation
Flexible
Grain growth
Grain size
Photoelectricity
Photovoltaic cells
Photovoltaics
Sb incorporation
Selenium
Solar cell
Solar cells
Solar energy
Surface roughness
Thickness
Thin films
Variation
Solar cell
CZTSSe
Flexible
PL
Sb incorporation
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Summary:•Evaporated Sb layer was inserted into CZTSSe precursor for the first time.•Hole concentration in CZTSSe was found to increase with Sb layer thickness.•The grain growth of CZTSSe benefited a lot from the introduced Sb layer.•The electrostatic potential fluctuation was reduced after the incorporation of Sb.•20 nm evaporated Sb layer took effect to the fullest extent in PCE enhancement. Cu2ZnSn(S,Se)4 (CZTSSe) chalcogenide with natural-abundance, environment -friendly and impressive photovoltaic performance is promising material for kesterite thin film solar cell. In this paper, the effects of evaporated Sb layer on performance of flexible CZTSSe thin film solar cell are investigated. Systematic studies show that the quasi-liquid Sb2Se3 plays productive roles in promoting grain growth, subsequently volatilizes in the elevated selenization temperature without entering into the CZTSSe lattice. Obvious improvements in crystallinity, grain size, surface roughness, hole concentration and device performance are obtained after optimizing the thickness of Sb layer. The electrostatic potential fluctuation extracted from the PL results is found to decrease from 115.9 meV to 60.7 meV after introducing 20 nm evaporated Sb layer. Finally, 20 nm evaporated Sb layer takes effect to the fullest extent which shows a 69% increase in photoelectric conversion efficiency (PCE). The incorporation of Sb opens up access to opportunity in roll-to-roll process for thin film solar cells.
ISSN:0038-092X
1471-1257
DOI:10.1016/j.solener.2019.09.073